Synthesis and near-infrared luminescence of a deuterated conjugated porphyrin dimer for probing the mechanism of non-radiative deactivation.

Frampton MJ, Accorsi G, Armaroli N, Rogers JE, Fleitz PA, McEwan KJ, Anderson HL

beta,meso,beta-Fused porphyrin oligomers have many attractive photophysical features such as strong absorption in the near-IR at wavelengths greater than 1000 nm, and high two-photon cross sections. However their ultrafast S(1)-S(0) deactivation (k(d) > 10(11) s(-1)) limits potential applications. We have synthesised a deuterated fused porphyrin dimer to test whether deuteration influences the rate of non-radiative deactivation. An efficient synthetic strategy was developed, starting with deuteration of dipyrromethane. Deuteration of the zinc porphyrin dimer does not affect its fluorescence quantum yield in CD(2)Cl(2)(Phi(fD)/Phi(fH)= 1.00 +/- 0.05). This implies that the ultrafast non-radiative deactivation is not simply a consequence of the small S(1)-S(0) energy gap. Comparison with other conjugated porphyrin oligomers confirms that the deactivation rate in the edge-fused oligomers is faster than would be expected from the energy gap law. This result indicates that it should be possible to create near-IR dyes with similar S(1)-S(0) energy gaps to the beta,meso,beta-fused porphyrin oligomers but with slower rates of S(1)-S(0) decay.

Keywords:

Dimerization

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Luminescence

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Magnetic Resonance Spectroscopy

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Metalloporphyrins

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Molecular Structure

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Porphyrins

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Reference Standards

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Sensitivity and Specificity

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Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization

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Spectrophotometry, Ultraviolet

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Spectroscopy, Near-Infrared

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Stereoisomerism

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Zinc